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Nickel alloys
Alloy 400

Ni-Cu alloy (Monel 400)

STANDARDASTM B164 / B127FORMBar, plate, forging, castingUNSN04400Material no.2.4360Cast counterpartM35-1 (ASTM A494)

Nickel-copper alloy. Very good resistance in seawater, hydrofluoric acid and caustic media; the classic material for seawater pump and valve stems and for valves in HF alkylation units.

Rp0.2 · MPa
—
Rm · MPa
—
TEMPERATURE
−196 … +475 °C
COST
Representative sample of Alloy 400: machined top face and rolled side
REPRESENTATIVE IMAGE

Chemical composition

Ni (+Co)≥ 63.0
Cu28.0–34.0
Fe≤ 2.5
Mn≤ 2.0
C≤ 0.3
Si≤ 0.5
S≤ 0.024

Mechanical properties

The values in this section are being verified.

Service temperature

ASME B16.34 group 3.4: −253 … 475 °C. Strength increases below zero without loss of ductility.

This is the limit of the material itself. A valve's service temperature is usually set by the seal and seat materials; product pages give it for each seal option.

Physical properties and heat treatment

DENSITY
8.80 g/cm³
MELTING RANGE
1300–1350 °C

Media suitability GENERAL TREND

Fresh water
Seawater
Steam
Hydrocarbons, oil
Dilute acid
Caustic
Air, gas
Low temperature

Emsal assessment. The final choice is made from corrosion tables, taking concentration, temperature, chloride content and flow velocity into account.

Strengths and weaknesses

Strengths

  • Very good resistance in flowing seawater
  • One of the few alloys resistant to hydrofluoric acid and caustics
  • Tough from cryogenic to moderate temperatures

Weaknesses

  • Pitting in stagnant seawater
  • Weak in oxidizing acids (nitric)
  • Expensive because of nickel and copper

Manufacturing and use

ECONOMY
High.
MANUFACTURING METHODS
Turning from bar · Forging · Casting (M35-1)
TYPICAL VALVE PARTS
Stem · Disc · Spring · Body (HF service)

Source: ASTM B164 / B127. Values compiled and verified by Emsal Vana; for binding values, refer to the current edition of the standard and the material certificate.